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Production and decay of sulfur excited species in an electron-cyclotron-resonance ion-source plasma

TitleProduction and decay of sulfur excited species in an electron-cyclotron-resonance ion-source plasma
Publication TypeJournal Article
Year of Publication2009
AuthorsMartins, M. C., Marques J. P., Costa A. M., Santos J. P., Parente F., Schlesser S., Bigot Le E. - O., and Indelicato P.
JournalPhysical Review A (Atomic, Molecular, and Optical Physics)
Volume80
Pagination032501
KeywordsDirac-Fock calculations, excited states, ground states, inner-shell ionisation, plasma sources, plasma X-ray sources, positive ions, radiative lifetimes, sulphur, X-ray spectra
AbstractThe most important processes for the creation of S12+ to S14+ ions excited states from the ground configurations of S9+ to S14+ ions in an electron cyclotron resonance ion source, leading to the emission of K x-ray lines, are studied. Theoretical values for inner-shell excitation and ionization cross sections, including double-KL and triple-KLL ionizations, transition probabilities and energies for the de-excitation processes, are calculated in the framework of the multiconfiguration Dirac-Fock method. With reasonable assumptions about the electron energy distribution, a theoretical Kalpha x-ray spectrum is obtained, which is compared to recent experimental data.
URLhttp://link.aps.org/abstract/PRA/v80/e032501